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ChemInform Abstract: 2′-Deoxy-2′-alkoxylaminouridines: Novel 2′-Substituted Uridines Prepared by Intramolecular Nucleophilic Ring Opening of 2,2′-O- Anhydrouridines.

✍ Scribed by D. P. SEBESTA; S. S. O'ROURKE; R. L. MARTINEZ; W. A. PIEKEN; D. P. C. MCGEE


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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S N 2 vs Intramolecular Oxygen Participation Reaction of 2-O-Triflylgluco-/ido-furanosides: Synthesis of C-5 Alkyl Substituted 2-Deoxy-2-azidosugars. -Triflates like (I) provide oxygen participated products (II) in the presence of NaN 3 , whereas reactants (IV) only furnish normal S N 2 products (V