✦ LIBER ✦
ChemInform Abstract: SN2 vs Intramolecular Oxygen Participation Reaction of 2-O-Triflylgluco-/ido-furanosides: Synthesis of C-5 Alkyl Substituted 2-Deoxy-2-azidosugars.
✍ Scribed by A. RANI; S. KATIYAR; S. N. SURYAWANSHI
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
S N 2 vs Intramolecular Oxygen Participation Reaction of 2-O-Triflylgluco-/ido-furanosides: Synthesis of C-5 Alkyl Substituted 2-Deoxy-2-azidosugars.
-Triflates like (I) provide oxygen participated products (II) in the presence of NaN 3 , whereas reactants (IV) only furnish normal S N 2 products (V) under the same conditions. -(RANI, A.