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ChemInform Abstract: 2-Benzothiazolyl Phenacyl Sulfoxide, a New Precursor for 2-Oxo-2-phenylethanethial.

โœ Scribed by Masahiro Takeda; Tadaaki Hashimoto; Takayoshi Fujii; Shin Ono.; Toshiaki Yoshimura; Choichiro Shimasaki; Hiroyuki Morita

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES

2-benzothiazolyl phenacyl sulfoxide, a n
2-benzothiazolyl phenacyl sulfoxide, a new precursor for 2-oxo-2-phenylethanethial
โœ Masahiro Takeda; Tadaaki Hashimoto; Takayoshi Fujii; Shin Ono; Toshiaki Yoshimur ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 156 KB

Previously, a facile formation of a thioaldehyde by the thermolysis of a heteroaryl phenacyl sulfoxide was confirmed by the detection of a cycloadduct with 2,3-dimethyl-1,3-butadiene. The usefulness of benzothiazolyl phenacyl sulfoxide as a precursor for 2-oxo-2-phenylethanethial was studied under t

ChemInform Abstract: A Simple Synthesis
ChemInform Abstract: A Simple Synthesis of New Carbinols from Bis(2-benzothiazolyl) Ketone.
โœ C. BOGA; L. FORLANI; P. E. TODESCO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 28 KB ๐Ÿ‘ 2 views

A Simple Synthesis of New Carbinols from Bis(2-benzothiazolyl) Ketone. -The addition of Grignard reagents to the title compund (II) affords the corresponding carbinols (IV) under mild conditions in excellent yields without any side products. Even bulky nucleophiles give almost quantitative yields.