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ChemInform Abstract: 2-Arylsulfinylmethyl Oxazines: Chiral Carbonyl Equivalents.

✍ Scribed by Kamaljit Singh; Prasant K. Deb; Sonia Behal


Book ID
101929185
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Behavior of Dioxola
✍ R. A. AITKEN; A. W. THOMAS πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 2 views

Behavior of Dioxolanones as Chiral Acyl Anion Equivalents. -Deprotonation of 1,3-dioxolan-4-ones [cf. (I)] and following alkylation gives products (III). Their flash vacuum pyrolysis yields ketones (IV) (with concomitant loss of CO and acetone) showing (I) to be acyl anion equivalents. Conjugate ad