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ChemInform Abstract: [1,5]-Hydride Transfer/Cyclizations on Alkynyl Fischer Carbene Complexes: Synthesis of 1,2-Dihydroquinolinyl Carbene Complexes and Cascade Reactions.

✍ Scribed by Jose Barluenga; Martin Fananas-Mastral; Fernando Aznar; Carlos Valdes


Publisher
John Wiley and Sons
Year
2008
Weight
45 KB
Volume
39
Category
Article
ISSN
0931-7597

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[1,5]-Hydride Transfer/Cyclization of or
✍ José Barluenga; Martín Fañanás-Mastral; Amadeo Fernández; Fernando Aznar 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 304 KB

## Abstract An efficient method for the synthesis of compounds containing a quinoline moiety by using __o__‐aminophenyl alkynyl Fischer carbene complexes as starting materials is described. The reaction is based on a cascade process involving [1,5]‐hydride transfer/cyclization to afford new alkenyl