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ChemInform Abstract: [1,5]-Hydride Transfer/Cyclization of ortho-Amino Alkynyl Fischer Carbene Complexes: A Useful Tool for the Synthesis of Quinoline Derivatives.

✍ Scribed by Jose Barluenga; Martin Fananas-Mastral; Amadeo Fernandez; Fernando Aznar

Publisher: John Wiley and Sons
Year: 2011
Weight: 31 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201130158

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[1,5]-Hydride Transfer/Cyclization of or

[1,5]-Hydride Transfer/Cyclization of ortho-Amino Alkynyl Fischer Carbene Complexes: A Useful Tool for the Synthesis of Quinoline Derivatives

✍ José Barluenga; Martín Fañanás-Mastral; Amadeo Fernández; Fernando Aznar 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 304 KB

## Abstract An efficient method for the synthesis of compounds containing a quinoline moiety by using __o__‐aminophenyl alkynyl Fischer carbene complexes as starting materials is described. The reaction is based on a cascade process involving [1,5]‐hydride transfer/cyclization to afford new alkenyl

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