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ChemInform Abstract: 1,3-Thiazepines. Part 4. Reaction of 2-Iminothiazepines with Methyl Acrylate. Crystal and Molecular Structure of 2-Phenylimino-3-(β- methoxycarbonylethyl)- and 2-Benzyliminohexahydro-1,3-thiazepines.

✍ Scribed by R. F. AMBARTSUMOVA; B. TASHKHODZHAEV; M. K. MAKHMUDOV


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


Part 4. Reaction of 2-Iminothiazepines with Methyl Acrylate. Crystal and Molecular Structure of 2-Phenylimino-3-(β-methoxycarbonylethyl)-and 2-Benzyliminohexahydro-1,3thiazepines.

-Reaction of 2-iminothiazepines (I) with methyl acrylate (II) proceeds at the endocyclic nitrogen to give the 2-imino-3-(βmethoxycarbonylethyl)-1,3-thiazepines (III) in high yields. The structure of the formed compounds is confirmed by X-ray crystallography on the phenyl derivative (IIIa).


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