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ChemInform Abstract: 1,3-Thiazepines. Part 1. Synthesis and Spectral Properties of 2- Iminohexahydro-1,3-thiazepines (IV).

✍ Scribed by R. F. AMBARTSUMOVA; M. G. LEVKOVICH; E. G. MIL'GROM; N. D. ABDULLAEV

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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1,3-Thiazepines. Part 2. Reaction of 2-Iminohexahydrothiazepines with Phenyl Isocyanate and Isothiocyanates. -Reaction of the iminothiazepines (I) with phenyl isocyanate (II) gives the expected ureas (III) in good yields. In contrast, reaction with aryl isothiocyanates in refluxing toluene produces