ChemInform Abstract: 1,3-Dipolar Cycloaddition of Nitrile Oxides to 2(5H)-Furanones Substituted at the 5-Position by Sulfur-Bearing Groups.
✍ Scribed by R. ALGUACIL; F. FARINA; M. V. MARTIN
- Book ID
- 112034017
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
The 1,3 dipolar cycloadditions of diazomethane and ethyl diazoacetate with differently substituted 5-mlfur-2(5/-/)-furanones (1-6) are rcpone~ Cycloaddition of diazomethane occurs in a regio-and ~¢ manner to give the ~ed adducts 9-14, in good yield. The cycloaddition with ethyl diazoat~ate occurs al
## Abstract Benzonitrile oxide cycloadds to the CC bond of substituted 4,5‐dihydro‐3‐methylene‐2(3__H__)‐furanones 1a–1g. Thus, (__E__)‐1a and (__E__)‐1b are converted into the corresponding isoxazolinespirodihydrofuranones (4__RS__,5__RS__)‐2a and (4__RS__,5__RS__)‐2b, and (__E__)‐1c is converted