Metal porphyrins catalyse luminol chemiluminescence at pH 13 without added peroxide. The effects of 22 different surface active compounds on this reaction were studied using six metal porphyrins and one metal porphyrin conjugate. The most active catalyst was PAn-meso-tetra(4-sulphonatophenyl)porphin
Chemiluminescence of CaH and AIH in the reaction of the metal atoms and formaldehyde
โ Scribed by K. Sakurai; A. Adams; H.P. Broida
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 237 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Strong infrared chemiluminescence, largely attributable to OCS, was observed in the reactions of 0 atoms with CS, in n fast flow svstem. Vibration&v excited CO was detected only weakly and at IO u
Product studies were made with the FlIR method in the photolysis of miwxes containing Cl2 and CH20 up to 1 torr each in i atm M-The formation of two principal products, HQ and HCCPO, can be accounted for by the chain photochlorination of CEEzO, ie\_. CL2 +hv -2Q,CItCH70~CHOi-Ha,CHO-Q, -+ HCCIO f CL
states are going to survive the trip and be able to exhibit some chemistry. The chemistry of the electronically excited state(s) can differ dramatically from that of the ground state, and one such system which nicely demonstrates this is the reaction of magnesium which alkyl halides (Scheme 11). -1