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Chemiluminescence enhancement of 1,2-di[3,4,5-tri(3,4,5-trihydroxybenzoyloxy)benzoyloxy] benzene in the presence of quaternary ammonium ions

✍ Scribed by Manabu Nakazono; Hiroki Agawa; Shinkoh Nanbu; Kiyoshi Zaitsu


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
375 KB
Volume
25
Category
Article
ISSN
1522-7235

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✦ Synopsis


Abstract

The chemiluminescence intensity of 1,2‐di[3,4,5‐tri(3,4,5‐trihydroxybenzoyloxy)benzoyloxy] benzene increased in the presence of quaternary ammonium ions, such as acetylcholine chloride, choline chloride or benzyltrimethylammonium chloride. The complex of 1,2‐di[3,4,5‐tri(3,4,5‐trihydroxybenzoyloxy)benzoyloxy] benzene with acetylcholine chloride, choline chloride or benzyltrimethylammonium chloride was investigated by ^1^H‐NMR spectroscopy. The structure of the complex formed from 1,2‐di[3,4,5‐tri(3,4,5‐trihydroxybenzoyloxy)benzoyloxy] benzene with choline chloride was described by an ab initio quantum chemical calculation. Copyright © 2010 John Wiley & Sons, Ltd.


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