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Chemically induced electron spin polarisation and radical pair re-encounters

โœ Scribed by P.W. Atkins


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
417 KB
Volume
18
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


A simple extension of the model of 3 radical pair is described in which the relntivc translational motion of the iadiculs is described by an exponential rranslational correlation function ior departure and rccncountcr. A variety of polarisations can be xcountcd fo: \Mlout invoking rc-encounters, although r*encounters can bc important in particular situations.


๐Ÿ“œ SIMILAR VOLUMES


Contribution of S0 โ†” Tยฑ1 intersystem cro
โœ F.J. Adrian ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 454 KB

It is found that intersgstem crossings between the singlet and the MS = fl components of the triplet state of radical p&in liquids can produce nuclear and electron spin polarizations when two radicals diffuse apart follOWing arl initial encounter and subsequently undergo a second nonreactive encount