Chemically induced electron spin polarisation and radical pair re-encounters
โ Scribed by P.W. Atkins
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 417 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
A simple extension of the model of 3 radical pair is described in which the relntivc translational motion of the iadiculs is described by an exponential rranslational correlation function ior departure and rccncountcr. A variety of polarisations can be xcountcd fo: \Mlout invoking rc-encounters, although r*encounters can bc important in particular situations.
๐ SIMILAR VOLUMES
It is found that intersgstem crossings between the singlet and the MS = fl components of the triplet state of radical p&in liquids can produce nuclear and electron spin polarizations when two radicals diffuse apart follOWing arl initial encounter and subsequently undergo a second nonreactive encount