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Chemically induced dynamic nuclear polarization. Decarboxylation of photochemically generated benzoyloxy radicals

✍ Scribed by J.A. den Hollander; J.P.M. van der Ploeg

Book ID
103400667
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
329 KB
Volume
32
Category
Article
ISSN
0040-4020

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πŸ“œ SIMILAR VOLUMES

Photochemically induced dynamic nuclear
Photochemically induced dynamic nuclear polarization of 9,10- diphenylanthracene endoperoxide
✍ FranΓ§oise Carissimo-Rietsch; Jean Marko; Gaston Vermeersch; Jean-Marie Aubry πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 616 KB

Ii and "C nuclear spin polarizations are observed during light irradiation of 9,10-diphenylanthraceene endoperoxide. It is shown that phenol and 10-hydroxy-10-phenyl-9-anthrone (HPA) are formed via a radical pair mechanism depending on the irradiation wavelength. The first step of the reaction consi