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Chemical Transformations of 9,11-Ethano-13,15-isoxazolinoprostanoids

✍ Scribed by N. F. Bondar'; L. P. Isaenya; R. V. Skupskaya; F. A. Lakhvich


Book ID
111608992
Publisher
SP MAIK Nauka/Interperiodica
Year
2003
Tongue
English
Weight
120 KB
Volume
39
Category
Article
ISSN
1070-4280

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ChemInform Abstract: Reductive Transform
✍ F. A. LAKHVICH; V. A. KOZINETS; YA. M. KATOK; E. V. KOROLEVA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 1 views

Reductive Transformations of 9-Oxo-11-deoxy-11-methyl-13,15isoxazoloprostanoids. -Reduction of the title prostanoids (I) with K-selectride affords the corresponding 9-hydroxy derivatives (II) in excellent Ξ±-selectivity. In contrast, in the presence of sodium borohydride a mixture of Ξ±-and Ξ²-hydroxy