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Chemical properties of 2,2,4-trisubstituted 2,3-dihydro-1H-1,5-benzodiazepines

โœ Scribed by V. D. Orlov; S. M. Desenko; N. S. Pivnenko

Book ID
104781619
Publisher
Springer US
Year
1987
Tongue
English
Weight
328 KB
Volume
23
Category
Article
ISSN
0009-3122

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โœฆ Synopsis

Acetylation and nitrosation of 2,4-diaryl-2-methyl-2,3-dihydro-iH-l,5-benzodiazepines take place at the azomethyne nitrogen. Reduction is stereoselective.

๐Ÿ“œ SIMILAR VOLUMES

2,4-Bis(4-chlorophenyl)-2-methyl-2,3-dih
2,4-Bis(4-chlorophenyl)-2-methyl-2,3-dihydro-1H-1,5-benzodiazepine
โœ An, Li-Tao ;Ding, Fei-Qing ;Zou, Jian-Ping ;Lu, Xiao-Hua ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 989 KB

In the title compound, C 22 H 18 C l2 N 2 , the seven-membered heterocyclic ring is in a boat-shaped conformation. The molecules are linked by N-Hร ร รN hydrogen bonding into one-dimensional chains along the [010] direction.