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Chemical polarization of protons in the decomposition reaction of di-tert-butyl peroxalate

✍ Scribed by A. V. Ignatenko; A. V. Kessenikh; S. V. Rykov


Book ID
112423120
Publisher
Springer
Year
1971
Tongue
English
Weight
78 KB
Volume
20
Category
Article
ISSN
1573-9171

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Decomposition of di-tert-butyl nitroxide
✍ T. CΓ‘ceres; C. UrzΓΊa; E. A. Lissi πŸ“‚ Article πŸ“… 1985 πŸ› John Wiley and Sons 🌐 English βš– 299 KB

Di-tert-butyl nitroxide (DTBN) decomposes in aqueous solutions producing 2-methyl-2-nitroso propane (MNP) and tert-butanol. The process is acid catalyzed, it is of second order in DTBN, and takes place with a rate constant of (1.0 2 0.1) M-\* s-'. The reaction is also catalyzed by the anionic surfac