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Chemical polarisation of electrons in redox reactions

✍ Scribed by V. F. Shuvalov; P. A. Stunzhas; A. P. Moravskii

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
225 KB
Volume
5
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

In the system Ti(III)ο£ΏH~2~O~2~ο£ΏRH (RH is isobutyric acid or isopropanol) the concentration and polarisation of the β‐radical decreases during the reaction, while the polarisation of the α‐radical increases with the decrease of the α‐radical concentration. The second fact is not in accordance with Adrian's model of inducing the polarisation in redox systems during the radical recombination process.

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