Chemical Physics of Decomposition of Energetic Materials. Problems and Prospects
β Scribed by L. P. Smirnov
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 15 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The gas products from rapid thermolysis of aminotetrazoles are discussed in terms of their potential to affect the burn rate of a composite propellant. 1,5-and 2,5-diaminotetrazole decompose by two competitive reactions. One reaction gives HCN, NH3, and N 2 and the other gives NtI2CN, NH3, and N 2.
The kinetics of thermal decomposition of hexanitrohexazaisowurtzitane (HNIW) were measured by the isothermal weight loss (TGA) and absorbance changes in the FTIR spectrum at 1 atm. Below 204"C, the initial 50% of decomposition follows the power rate expression k(T)(l -cO n with n = 1,2. The activati
## Abstract Temperature profiling/FTIR is described for the fast thermolysis of four CβNO~2~βcontaining nitramines whose oxygen content exceeds the balance to CO~2~. The compounds are [(NO~2~)~3~CCH~2~N(NO~2~)CH~2~β]~2~ (ONDO), [(NO~2~)~3~CCH~2~]~2~N(NO~2~) (BTNEN), [Cl(NO~2~)~2~CCH~2~]~2~N(NO~2~)