Thermal Decomposition of Energetic Materials XVIII. Bis (cyanomethyl)nitramine and Bis(cyanoethyl)nitramine
β Scribed by Y. Oyumi; A. L. Rheingold; T. B. Brill
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 617 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0721-3115
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## Abstract Temperature profiling/FTIR is described for the fast thermolysis of four CβNO~2~βcontaining nitramines whose oxygen content exceeds the balance to CO~2~. The compounds are [(NO~2~)~3~CCH~2~N(NO~2~)CH~2~β]~2~ (ONDO), [(NO~2~)~3~CCH~2~]~2~N(NO~2~) (BTNEN), [Cl(NO~2~)~2~CCH~2~]~2~N(NO~2~)
High-rate thermolysis data for two primary linear nitramines and three secondary linear nitramines are compared to evaluate the effect of differences in the composition of the backbone on evolved gas products. The primary nitramines retain the N-N bonds but undergo C-N bond fission, while the second