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Chemical Methods for Ether-Bond Cleavage by Electron-Transfer Reagents

✍ Scribed by Zbigniew Grobelny

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 188 KB
Volume: 2004
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200400004

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✦ Synopsis

Abstract

Ethers can easily be cleaved with various electron‐transfer reagents. New data concerning the chemical methods of the regioselective opening of the ether bond with alkali metals (M^0^), alkali metal aromatic radical anions (Ar**^·^**^−^, M^+^), alkalides (M^−^, M^+^C; C denotes a ligand) and low‐valent transition‐metal compounds are presented. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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