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Chemical Methods for Ether-Bond Cleavage by Electron-Transfer Reagents

✍ Scribed by Zbigniew Grobelny


Publisher
John Wiley and Sons
Year
2004
Weight
10 KB
Volume
35
Category
Article
ISSN
0931-7597

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Chemical Methods for Ether-Bond Cleavage
✍ Zbigniew Grobelny πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 188 KB

## Abstract Ethers can easily be cleaved with various electron‐transfer reagents. New data concerning the chemical methods of the regioselective opening of the ether bond with alkali metals (M^0^), alkali metal aromatic radical anions (Ar**^Β·^**^βˆ’^, M^+^), alkalides (M^βˆ’^, M^+^C; C denotes a ligand

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Thermodynamic stability properties of 11 p-substituted trityl and seven 9-phenylxanthyl carbocations are reported in sulfolane and of their conjugate carbanions in DMSO. The cations are compared by calorimetric heats of hydride transfer from cyanoborohydride ion, their first and second reduction pot