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Chemical ionization mass spectrometry of some monoterpene gentianine alkaloids and their derivatives

✍ Scribed by Vasil A. Popov; Nevena N. Mollova; Simona M. Veleva; Simeon S. Popov


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
392 KB
Volume
21
Category
Article
ISSN
1076-5174

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✦ Synopsis


The chemical ionization mass spectra of eight monoterpene alkaloids from the gentianine group and their derivatives were investigated. Isobutane, methanol, ammonia, methylamine, ethylenediamine, diethylamine and triethylamine were used as reactant gases. The application of this technique for investigation of alkaloid mixtures and differentiation of proton affinities is demonstrated.

loids and only electron impact ionization (EI) was used for these investigation^.^*^


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## High -performance liquid chromatography/atmospheric pressure chemical ionization mass spectrometry (HPLC/APCI-MS) is a very promising approach to structural investigations of positional isomers and stereoisomers. This method was applied successfully to stereoisomeric norditerpenoid alkaloids dif