Chemical Design of High Spin Polynuclear Manganese(II) and Iron(II) Carboxylates
β Scribed by M. A. Kiskin; I. L. Eremenko
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 11 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Specific beat me~u~ments for Fe(phy)\*~~O~)~ and Fe(pby)\*(BF~)~ are reported in the spin transition region. A maximum in C, is observed at & due to the &t-order character of the spin-state transition. The value of C,, for high-spin states is greater than that for low-spin states. The derived values
The Fe"(TRIM),(PhCO,) (ClO,) spin crossover complex (TRIM = 4'-(4-methylimidazole )-2'-(2"-methylimidazole) imidazole, PhCOr = C6H5C02) has been synthesized and investigated by Miissbauer spectroscopy and magnetic susceptibility measurements as a function of temperature. The spin conversion is gradu