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Chemical Design of High Spin Polynuclear Manganese(II) and Iron(II) Carboxylates

✍ Scribed by M. A. Kiskin; I. L. Eremenko


Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


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Specific beat me~u~ments for Fe(phy)\*~~O~)~ and Fe(pby)\*(BF~)~ are reported in the spin transition region. A maximum in C, is observed at & due to the &t-order character of the spin-state transition. The value of C,, for high-spin states is greater than that for low-spin states. The derived values

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The Fe"(TRIM),(PhCO,) (ClO,) spin crossover complex (TRIM = 4'-(4-methylimidazole )-2'-(2"-methylimidazole) imidazole, PhCOr = C6H5C02) has been synthesized and investigated by Miissbauer spectroscopy and magnetic susceptibility measurements as a function of temperature. The spin conversion is gradu