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Chemical Bonding in Metallic Rutile-Type Oxides TO2 (T: Ru, Rh, Pd, Pt).

✍ Scribed by Gerard Demazeau; Samir F. Matar; Rainer Poettgen

Publisher: John Wiley and Sons
Year: 2007
Weight: 11 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200737002

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Abstract

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Investigations of three systems lead to the stabilization of new pseudo-ternary RT(T' 0.5 X 1.5 ) and R 3 T 2 T' 2 X 4 compounds with TbFeSi 2 and U 3 Ni 4 Si 4 -type structures. These are characterized by a stacking of RT 2 X 2 (BaAl 4 -type) and RT'X (AlB 2 -type) layers. Therefore, the new alloys