The reaction responsible for chemi-ion formation in hydrocarbon flames, CH + O-tHCO+ +e-, may require that the CH be in its metastable a 'Z state. Recently measured rate constants for reactions of ground stale CH (X 'II) with various molecules are incompatible with the empirical rate law for chemi-i
Chemi-ionization produced by the catalytic combustion of a hydrocarbon
β Scribed by S.D.T. Axford; W. Cai; A.N. Hayhurst; N. Collings
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 422 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0010-2180
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An experimental method based on the detection of the enhancement of chemi-ionization following the pulsed laser excitation of CH\*(A \*A, B 'Z-) radicals is described. This approach provides conclusive and direct obserwtions of chemiionization reactions involving Cil\*(A 2~, B',r-) radicals. The re
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