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Chelation-controlled chemo-, regio- and enantio-selective synthesis of homoallylic alcohols

✍ Scribed by Vincenzo Caló; Vito Fiandanese; Angelo Nacci; Antonio Scilimati

Book ID: 104203186
Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 630 KB
Volume: 50
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)85251-0

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✦ Synopsis

Optimily active allylic sulphidcd 10-13, bearing two difiuent leaving groups. at with orgsnocoppet reagents by selective salwtitalioa of the hetemcyclic moiety leading to opdcally active homoallylic pivalates with cbemo-. regie aad enaatiocaotrd.This~~ivity~toberelatedtathecooldirmtionexatadbythehetaDcyclcn~~towardsthenganometal.

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