Specific features of the charge-transfer (CT) states and O 2p ! Ni 3d CT transitions in the octahedral Γ°NiO 6 Γ 10Γ complex are considered in the cluster approach. The reduced matrix elements (RMEs) of the electric-dipole transition operator are calculated on many-electron wave functions of the comp
Charge-transfer transitions and optical spectra of vanadates
β Scribed by A. V. Zenkov
- Book ID
- 110141491
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2005
- Tongue
- English
- Weight
- 534 KB
- Volume
- 47
- Category
- Article
- ISSN
- 1063-7834
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Optical transitions in normal-spinel Co 3 O 4 have been identified by investigating the variation of its optical absorption spectrum with the replacement of Co by Zn. Three optical-transition structures were located at about 1.65, 2.4, and 2.8 eV from the measured dielectric function of Co 3 O 4 by
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