<p>This book presents an account of the NATO Advanced Study Institute on "Energy Transfer Processes in Condensed Matter", held in Erice, Italy, from June 16 to June 30, 1983. This meeting was organized by the International School of Atomic and Molecular Spectroscopy of the "Ettore Majorana" Centre f
Charge Transfer Processes in Condensed Media
β Scribed by Jens Ulstrup (auth.)
- Publisher
- Springer-Verlag Berlin Heidelberg
- Year
- 1979
- Tongue
- English
- Leaves
- 426
- Series
- Lecture Notes in Chemistry 10
- Edition
- 1
- Category
- Library
No coin nor oath required. For personal study only.
β¦ Synopsis
Molecules in liquid and solid media are exposed to strong interΒ action forces from the surrounding medium. The formulation of a comprehensive theory of chemical processes in condensed media is consequently an elaborate task involving concepts from several areas of the natural sciences. Within the las~ two and a half decades very notable results towards the formulation of a 'unified' quantum mechanical theory of such processes have in fact been achieved, and by the variety of physical, chemical, and biological processes which can be suitably covered by this framework, the new theory represents an adequate alternative to the transition state theory. The present work has a two-fold purpose. Firstly, to provide a reasonably organized exposition of some basic aspects of these developments. This part emphasizes the fundamental similarities between chemical and other kinds of radiationless processes and includes the derivation of the most important rate expressions without resorting to involved mathematical techniques. The s- ond major purpose is to illustrate the 'unified' character of the rate theory by analysis of a considerable amount of expe- mental data from both 'conventional' kinetics and from such untraditional areas as low-temperature, strongly exothermic, and biological processes. Particular attention is here given to those systems for which a classical description is inadequate, and which provide a diagnostic distinction between several alternative theoretical approaches.
β¦ Table of Contents
Front Matter....Pages I-VII
Introduction....Pages 1-39
Multiphonon Representation of Continuous Media....Pages 40-70
Quantum Mechanical Formulation of Rate Theory....Pages 71-141
The Effect of Intramolecular Modes....Pages 142-170
Semiclassical Approximations....Pages 171-208
Atom Group Transfer Processes....Pages 209-256
Higher Order Processes....Pages 257-294
Electrochemical Processes....Pages 295-338
Application of the Rate Theory to Biological Systems....Pages 339-372
Back Matter....Pages 373-419
β¦ Subjects
Chemistry/Food Science, general
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