Charge transfer in thin films of donor–acceptor complexes studied by infrared spectroscopy
✍ Scribed by Diana Nanova; Sebastian Beck; Andreas Fuchs; Tobias Glaser; Christian Lennartz; Wolfgang Kowalsky; Annemarie Pucci; Michael Kroeger
- Book ID
- 113834488
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 980 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1566-1199
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Static quenching (T=77K) of luminescence of naphthalene derivatives via CT complexes in solid state with tetracyanoethylene has been studied. The linear correlation between the logarithm of K quenching constant and 1 Q CT frequency in electronic absorption spectra of CT complexes has been observed.
## Abstract The photo‐induced “charge‐transfer” copolymerization of various donor monomer‐acceptor monomer pairs was studied by irradiation of their CT complexes with 365 nm light. The influence of the donor and acceptor strength on the rate of polymerization shows that stronger donor/weaker accept