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Charge reversal of the enolate ions of acetaldehyde and acetone

✍ Scribed by Thomas A. Lehman; Maurice M. Bursey; J. Ronald Hass

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
514 KB
Volume
18
Category
Article
ISSN
1076-5174

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✦ Synopsis

CoUisionaUy activated charge reversal of HCOCH,-and CH3COCHz-produces positive ions whose fragments M e r from those of other [GH30]+ ions formed by fragmentation of positive molecular ions, including the [GH30]' ions from 2,2-&chloroethanol, considered formerly to have the HCOCHz+ structure. The fragmentations of the charge reversed ions are concordant with the RCOCHt' structures. Least-squares correlations of the collisional activation spectra [GH30]+ are probed as a useful guide to claiming similarity or dissimilarity of ionic structure.

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