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Vibrational fine structure in the collisionally induced charge reversal and fragmentation of OH− ions

✍ Scribed by John L. Holmes; Jan E. Szulejko


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
473 KB
Volume
106
Category
Article
ISSN
0009-2614

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✦ Synopsis


OH+ or OD+ ions were generated by collisionally induced charge reversal of the corresponding anions and then submitted to collisionally induced dissociation to H+ and D+. The resulting ion kinetic energy spectra showed multiple vibrational time structure which were assigned to pred~sociations from the a 'A state. UnimoIecular dissociation of OH+ and OD+ lo yield O+ gave a single-valued kinetic energp release for predissociation of the 1 II state.


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