Charge redistribution and polarization effects on the solvation energy of ions
โ Scribed by Antonio Raudino
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 879 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The solv3rochromlccqu311ons dcscnbmg rbe cifects of solvent polar~ty/polwizab~hty (IT\*), solvenr hydrogen band donor acIdtry (a). and solbent hydrozcn bond xccptor bJsiaty (I?) have been determmed for scvcd Iluabundazole homologurs The s rosificlcnt ws iound to bc hnearly rclstcd to rhe Hammett o\*
The use of a linear relationship between free energy of hydrophobic hydration and solvent-accessible apolar surface area has been helpful in interpreting the thermodynamics of biological macromolecules. However, a recent study (Y.-K. Cheng, P. J. Rossky, Nature 1998, Vol. 392, pp. 696-699) has estab
The hydrarion enerpies for rhc NH: and CH3NH; ions wxc calculated by an ab initio MO method. The aqueous SCJ~KIlion cnrrgy diffcrencc bctwccn these IWO ions WCIS found to be accounted for by the interactions of the ions with a few sol-VClll 111111ecu1rs.