Charge on the move: how electron-transfer dynamics depend on molecular conformation
โ Scribed by Benniston, Andrew C. ;Harriman, Anthony
- Book ID
- 124168973
- Publisher
- Royal Society of Chemistry
- Year
- 2006
- Tongue
- English
- Weight
- 555 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0306-0012
- DOI
- 10.1039/B503169A
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๐ SIMILAR VOLUMES
The influence of solvent polarity on spectroscopic and thermodynamic properties of molecular electron-donor-acceptor (EDA) complexes is discussed. Analysis of experimental data leads to the conclusion that the ground state of EDA complex is destabilized with increasing polarity of solvent and this i
The present work rests on non-adiabatic electron transfer theory. The influence of the molecular dynamics (MD) of exchanging groups on the electron transfer rate is treated. The MD of exchanging groups is described as a stochastic process with two possible states. The transfer between these two stat