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Charge motion effects in ionic clusters

✍ Scribed by Isidore Last; Thomas F. George

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 371 KB
Volume: 183
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(91)80173-u

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✦ Synopsis

In ionic clusters the polarization depends on the dynamics of charge delocalization. The polarization follows the charge motion when the characteristic time of motion is much longer than the polarization time (adiabatic polarization ). For the opposite case (diabatic polarization), the polarization is determined by an average field. These two kinds ofpolarization are considered for the ionic clusters Xc: R and benzene+-R (R= He, Ne, Ar).

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