In the mass spectra of several transition metal chelates with diethyldithiocarbamate as a ligand, intense peaks are present which could be assigned to extraneous metal (particularly nickel) containing ions. Using an Au-Rh coated ion source, evidence was obtained for the occurrence of exchange reacti
✦ LIBER ✦
Charge exchange ion formation between the source and electric sector of a mattauch—herzog mass spectrometer
✍ Scribed by J.M. McCrea
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 303 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0020-7381
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## Abstract The apperrance of peaks at non‐integral masses in linked scans, where the ratio __B__/__E__ is kept constant, is shown to be caused by fragmentations of metastable ions occuring in the region between the magnetic and electric sectors. A formula is given for calculating the mass of the p