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Characterizing the Behavior and Properties of an Excited Electronic State: Electron-Transfer Mediated Quenching of Fluorescence

✍ Scribed by Poulsen, Lars; Ruiz, Arantza Zabala; Pedersen, Steen Uttrup; Ogilby, Peter R.


Book ID
120420744
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
98 KB
Volume
80
Category
Article
ISSN
0021-9584

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Excited-state electron-transfer quenchin
✍ Edmond Amouyal; Bertrand Zidler; Patrick Keller; Alec Moradpour πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 310 KB

Rate constants kq for the quenchmg of the exated state of Ru@rpy)~+ by a serves of vrologen salts havmg drfferent redo\ potentral El,2 hare been determmed in daerated aqueous solutrons at pH = 5 by laser flash photolysls The kq values are found to decrease v. rth mcreasmg -E, ,\* and to correlate wi