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Proton and Electron Transfer in the Excited State Quenching of Phenosafranine by Aliphatic Amines

✍ Scribed by Martín F. Broglia; Sonia G. Bertolotti; Carlos M. Previtali


Book ID
111837425
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
815 KB
Volume
83
Category
Article
ISSN
0031-8655

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The quenching of n,p\* singlet-excited 2,3-diazabicyclo[2.2.2]oct-2-ene, a very weak electron acceptor, by 26 aliphatic and aromatic amines was investigated in benzene. This photoreaction entails fluorescence quenching through exciplex formation with subsequent hydrogen atom abstraction from the N-H