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Characterization of Two Chloro-Substituted m -Benzyne Isomers: Effect of Substitution on Reaction Efficiencies and Products

✍ Scribed by Price, Jason M.; Kenttämaa, Hilkka I.


Book ID
126429802
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
282 KB
Volume
107
Category
Article
ISSN
1089-5639

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## Abstract The solvent effect on a nucleophilic substitution reaction of 2‐ and 4‐chloro‐3,5‐dinitrobenzotrifluoride with substituted anilines was studied in methanol, acetonitrile, and toluene at 25°C. This reaction is of second order, except 2‐chloro‐3,5‐dinitrobenzotrifluoride in toluene shows