Characterization of thiocarbonyl ylides in the reaction of triplet carbenes with thioketones
β Scribed by W.G McGimpsey; J.C Scaiano
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 217 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The reactions of fluorenylidene and diphenyl carbene with di-tert-butylthioketone and adamantanethione lead to the rapid formation of strongly absorbing, long-lived ylides.
π SIMILAR VOLUMES
A thiocarbonyl ylide generated by sila-Pummerer rearrangement of bis(trimethylsilylmethyl) sulfoxide reacted with C6o to give a tetrahydrothiophene-fused C6o derivative. The cycloadduct was readily oxidized with mCPBA to give the corresponding sulfoxide and sulfone derivatives, which are useful for
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