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Characterization of the Transient Species Formed during the Pulse Radiolysis of 3-Hexyn-1-ol and 5-Hexyn-1-ol in Aqueous Solutions

✍ Scribed by Naik, Devidas B.; Dey, Ghasi Ram; Kishore, Kamal; Moorthy, Pervaje N.


Book ID
125986992
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
165 KB
Volume
101
Category
Article
ISSN
1089-5639

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The hydroxyl radical reaction rate const
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## Abstract A bimolecular rate constant,__k__~DHO~, of (29 Β± 9) Γ— 10^βˆ’12^ cm^3^ molecule^βˆ’1^ s^βˆ’1^ was measured using the relative rate technique for the reaction of the hydroxyl radical (OH) with 3,5‐dimethyl‐1‐hexyn‐3‐ol (DHO, HCο£½CC(OH)(CH~3~)CH~2~CH(CH~3~)~2~) at (297 Β± 3) K and 1 atm total pres