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Characterization of the Bi53+ cluster cation: Preparation of single crystals, crystal and molecular structure of Bi5(AlCl4)3

✍ Scribed by Bernt Krebs; Marita Mummert; Claus Brendel

Book ID
116015766
Publisher
Elsevier Science
Year
1986
Weight
670 KB
Volume
116
Category
Article
ISSN
0022-5088

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## Abstract The preparation and single crystal growth of bis(tetrabutylammonium)bis(4,5‐dithiolato‐1,3‐dithiole‐2‐thione)copper, (I), are described. The energy gap Eg of (I) is about 2.38 eV. The nonlinear optical susceptibility Ο‡^(3)^ is about 1.3Γ—10^‐3^ esu at 1064 nm. The characterization of (I)