A~tract--A method has been developed to synthesize cyclic polystyrene molecules, by reacting bifunctional "living" polystyrene with ~,~' dibromo-p-xylene. The ability of the method to yield cyclic polymers over a molecular weight range from 7000 to 250,000 has been thoroughly investigated and discus
Characterization of ring-shaped polystyrene
β Scribed by He Zhiduan; Yuan Meina; Zhang Xuanqi; Wang Xiaobing; Jin Xiaoming; Huang Jiaxian; Li Chunrong; Wang Linfu
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 266 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0014-3057
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β¦ Synopsis
A~tract--Fractions of ring-shaped polystyrene (RPS) of high molecular weight, and comparable samples of linear polystyrene (LPS), were characterized by gel permeation chromatography combined with laserlight scattering and by dilute solution viscometry. The ratio of intrinsic viscosities, g = [q],/[q]/= 0.65, and the ratio of unperturbed mean square radii of gyration, Go = (R ~ ),,,.
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Ring-shaped macromolecules have been synthesized by the reaction of a bifunctional "'living" polystyrene with a stoichiometric amount of dibromo-p-xylene, at very low concentration. The reaction is carried out step by step, leading both to the expected cyclic polymer and to a "polycondensate'. Fract
## Abstract A series of wellβdefined miktocycle numberβeightβshaped copolymers composed of cyclic polystyrene (PS) and cyclic poly(Ξ΅βcaprolactone) (PCL) have been successfully synthesized by a combination of atom transfer radical polymerization (ATRP), ringβopening polymerization (ROP), and βclickβ