For two-component mixtures, Kebarle and Tang observed that the ionization efficiency (i.e., yield of ions per unit concentration) depends strongly on the concentration and nature of other ionizable species and weakly on total concentration of ionized species. In this work, the model used by Kebarle
Characterization of must and wine of six varieties of grapes by direct infusion electrospray ionization mass spectrometry
✍ Scribed by Rodrigo R. Catharino; Ildenize B. S. Cunha; Aline O. Fogaça; Elizete M. P. Facco; Helena T. Godoy; Carlos E. Daudt; Marcos N. Eberlin; Alexandra C. H. F. Sawaya
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 349 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1076-5174
- DOI
- 10.1002/jms.976
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Samples of must derived from six different varieties of grapes taken during the fermentation process, as well as the respective wine samples directly after the end of the malolactic fermentation, were analyzed by direct infusion negative ion mode electrospray ionization mass spectrometry (ESI‐MS). Diagnostic ions for must were different from those of wine samples, although small variations for each of the grape varieties were also detected. The addition of unfermented must or sugar to wine could also be clearly detected. The spectra were acquired in a few minutes per sample, indicating that ESI‐MS can be used for high‐throughput analysis of samples and should prove useful for quality control during and after the fermentation process. Copyright © 2005 John Wiley & Sons, Ltd.
📜 SIMILAR VOLUMES
## Electrospray Ionization Mass Spectrometry (ESI-MS) obtained clearly indicate that the exchange reactions between water and methanol molecules, within the measurements and ab initio calculations on [OV(O 2 )(H 2 O) m -(CH 3 OH) n ] + (m,n: 0-4) peroxo cations have been carried out. coordination
## Abstract Photodegradation of the insecticide thiamethoxam (1), 3‐[(2‐chloro‐5‐thiazolyl)methyl]tetrahydro‐5‐methyl‐__N__‐nitro‐4H‐1,3,5‐oxadiazin‐4‐imine, in an aqueous medium was monitored by electrospray ionization mass spectrometry in the positive ion mode, ESI(+)‐MS. An aqueous solution of (
High resolution mass spectrometry on time-of-flight (TOF) and ion trap (IT) mass spectrometers is used for the qualitative speciation of a heterodimetallic triple-stranded helicate [EuFe(L 1 ) 3 ](CIO 4 ) 5 and a toroidal complex [Ni 3 (L 2 ) 3 ](CIO 4 ) 6 (= circular single-stranded helicate) disso
## Abstract A series of chalcones were characterized by electrospray ionization tandem mass spectrometry (MS^__n__^). Several ionization modes were evaluated, including protonation, deprotonation and metal complexation, with metal complexation being the most efficient. Collision‐activated dissociat