Characterization by NMR of reactants and products of hydrofluoroether isomers, CF 3 (CF 2 ) 3 OCH 3 and (CF 3 ) 2 C(F)CF 2 OCH 3 , reacting with isopropyl alcohol
β Scribed by Knachel, Howard C.; Benin, Vladimir; Moddeman, William E.; Birkbeck, Janine C.; Kestner, Thomas A.; Young, Tanya L.
- Book ID
- 121248326
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 570 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.3964
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π SIMILAR VOLUMES
## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical
## Abstract Rate constants for the gasβphase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d
## Abstract The intermolecular interaction energy curves of CH~3~OCH~3~ο£ΏCH~2~F~2~, CF~3~OCH~3~ο£ΏCH~2~F~2~, CF~3~OCF~3~ο£ΏCH~2~F~2~, CH~3~OCH~3~ο£ΏCHF~3~, CF~3~OCH~3~ο£ΏCHF~3~, and CF~3~OCF~3~ο£ΏCHF~3~ complexes were calculated by the MP2 level __ab initio__ molecular orbital method using the 6β311G\*\* basi