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Characterization and reduction of interferences in flow-injection analysis for the in situ determination of nitrate and nitrite in sea water

✍ Scribed by Anne Daniel; Dominique Birot; Michel Lehaitre; Jacques Poncin


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
947 KB
Volume
308
Category
Article
ISSN
0003-2670

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✦ Synopsis


The aim of this work is to improve the precision and the sensitivity of nitrite and nitrate determination by flow-injection analysis (FIA) for an in situ utilization. Two kinds of signal treatment are proposed in order to eliminate the refractive index provoked by the heterogeneous flow in FIA and the errors induced by temperature, salinity and pressure variations. The concentration range of this method is O-100 PM NO;-N with a detection limit (3cr,) of 0.45 PM NOT-N (A, = 0.1.51C,oi + 0.072, n = 40, r2 = 0.997). The relative standard deviation is 5% for nitrate solutions containing 0.5 PM NOT-N. The sampling rate is about 45 hh'.


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