DetectIon unth two polarized platmum wne electrodes 1s based on the oxldatlon of lodlde by mtnte The current IS proportlonal to the amount of lodme formed The Injected sample is spht m a flow-mlection mamfold mto two segments One of them 1s transported through a reductor mmlcolumn contammg coppenzed
Characterization and reduction of interferences in flow-injection analysis for the in situ determination of nitrate and nitrite in sea water
β Scribed by Anne Daniel; Dominique Birot; Michel Lehaitre; Jacques Poncin
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 947 KB
- Volume
- 308
- Category
- Article
- ISSN
- 0003-2670
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β¦ Synopsis
The aim of this work is to improve the precision and the sensitivity of nitrite and nitrate determination by flow-injection analysis (FIA) for an in situ utilization. Two kinds of signal treatment are proposed in order to eliminate the refractive index provoked by the heterogeneous flow in FIA and the errors induced by temperature, salinity and pressure variations. The concentration range of this method is O-100 PM NO;-N with a detection limit (3cr,) of 0.45 PM NOT-N (A, = 0.1.51C,oi + 0.072, n = 40, r2 = 0.997). The relative standard deviation is 5% for nitrate solutions containing 0.5 PM NOT-N. The sampling rate is about 45 hh'.
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