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Characteristics of thermotropic copolymer films cast from solution

✍ Scribed by R. J. Spontak

Book ID
104910824
Publisher
Springer
Year
1990
Tongue
English
Weight
301 KB
Volume
9
Category
Article
ISSN
0261-8028

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Domain structure of amorphous block copo
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## Abstract Three types of domain structures, namely spherical, rodlike, and lamellar, of A‐B and A‐B‐A (or B‐A‐B) block copolymers cast from solutions are discussed on the basis of a criterion that the structures originate at a critical micelle concentration as a result of microphase separation of

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Films of block eopolymers of polystyrene + isoprene, cast from cyciohexane at temperatures above and below a conformational transition temperature (Tp) derived from the plot of ['/l vs. T, have been examined for glass transition temperatures. In every case, two glass transitions were found, Twl (pol