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Characteristics of the reduction of the Cu-citrate complexes at the HMDE and DME

✍ Scribed by S. González; S.V. Alvarez; A. Arévalo

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
358 KB
Volume
28
Category
Article
ISSN
0013-4686

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✦ Synopsis

A study of the electrochemical behaviour of Cu(II) at the hmde and dnw with citric acid as supporting electrolyte at different pHs is presented. The complex Cwcitrate species which originate the voltammetrlc curves are determined and the existence of a binuclear complex accounting for the appearance of a second wave in the voltammograms is confirmed. The nature of the voltammetric maximum, which appears immediately after the current attains the value of i p, is i.nterpreted with regard to inhomogeneous adsorption of thereactant on the surface of the electrode. The mmmmm ofthedc polarograms is attributed to

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