Changes in the chemical potential of transition states on transfer from dimethylformamide to ethanol
β Scribed by I.P. Evans; A.J. Parker
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 181 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Western Australia, Because saturated solutions of the salt, AB, have the same chemical potential, the reactant, AB, in reaction [l] starts at the same free energy level in all solvents. Therefore the difference in initial rates of [l] (in moles litre -1 set-1) gives th e change in the chemical potential of unimolar solutions of the transition state AB", on transfer from one solvent to the other.*
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## Abstract The isobutane chemical ionization (CI) mass spectra of __cis__β and __trans__β1,4βdi(alkoxymethyl)cyclohexanes, with a tertiary alkoxy group ROH and a primary group Rβ²OH, are identical, and they exhibit exclusive elimination of the alcohol ROH originating from the tertiary alkoxyl. The