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Change of Sign of the Boron—Fluorine Spin—Spin Coupling Constant in the Tetrafluoroborate Anion

✍ Scribed by Gillespie, R. J.


Book ID
126494399
Publisher
American Institute of Physics
Year
1966
Tongue
English
Weight
288 KB
Volume
45
Category
Article
ISSN
0021-9606

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Theoretical study of the sign of the 1J(
✍ V. Galasso 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 228 KB

Non-empirical calculations using the equations-of-motion approach are reported for iJ( 15Nt5N) in hydrazine, diazene, isodiazene, the azide anion, and nitrogen. Irrespective of the single or multiple nature of the bond between the nitrogens, iJ( isNi5N) should be negative in all compounds. The only