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Change in electron structure of cyclic oxides during their interaction with electron acceptors. Quantum chemical investigation

โœ Scribed by N. M. Geller; Yu. Ye. Eizner; V. A. Kropachev


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
515 KB
Volume
32
Category
Article
ISSN
0323-7648

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Correlation between the electronic struc
โœ N. M. Geller; Yu. Ye. Eizner; V. A. Kropachev ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 277 KB ๐Ÿ‘ 2 views

I t is shown that cyclic oxides can be anionically polymerized if the lowest vacant molecular orbital (LVMO) of a C, atom contains a region which can effectively overlap by the electronic cloud of the anionic active centre. This means that LVMO must be a-symmetrical and a t least one of the C, atoms